硅中硼离子注入的带电缺陷动力学模拟

Dynamics Modeling of Charged Defects in Si under B Ion Implantation

  • 摘要: 为准确描述硼离子注入硅后缺陷/杂质的动力学物理过程,获得硼浓度空间分布及其演化行为,构建一个跨尺度带电缺陷动力学模型,考虑离子注入缺陷的产生及其演化的多种微观过程,包括缺陷电荷态和带电缺陷间的反应、硼-自间隙团簇(BICs)演化以及缺陷与载流子相互作用等物理过程。模拟得到与实验一致的硼浓度深度分布。结果表明:BICs对硼浓度的深度分布起主要作用,而间隙硼(BI)导致硼浓度分布向深处扩展;计及缺陷的不同电荷态修正自间隙(I)和硼间隙(BI)的扩散系数,从而更准确地描述硼浓度分布。模型揭示了硼离子注入硅发生的物理过程和微观机理,证明BICs和缺陷真实的电荷态是描述硼浓度分布的重要因素,为半导体器件制造与研发提供理论指导。

     

    Abstract: To describe accurately the dynamic physical process and obtain quantitatively boron (B) spatial distribution as well as it's evolution behaviors in silicon (Si) under boron implantation, we built a multiscale dynamic model of charged defects. In the model, multiple microscopic processes of defects generation and evolution are comprehensively considered under B ion implantation, including charge states of defects and reactions among charged defects, evolution of B-interstitial clusters (BICs) and interactions between charged defects and carriers. The simulated B distribution is consistent with experiments. It shows that BICs dominate the depth distribution of B concentration and interstitial B (BI) makes B distribution extend into depth. Besides, considering charge states of defects, we correct diffusion coefficients of Si interstitials (I) and BI so that the behavior of B distribution can be described accurately. The model reveals real physical processes and micro-mechanisms in Si under B implantation, which demonstrates that BICs and real charge states of defects are the key in describing B distribution. It provides theoretical guidance for semiconductor device fabrication.

     

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