Ni(mpz)<sub>4</sub>Cl<sub>2</sub>型化合物光磁性质的理论研究

Ni(mpz)₄Cl₂型化合物光磁性质的理论研究

摘要: 利用d⁸(D_4h^*)全组态混合统一晶场理论对Ni(mpz)₄Cl₂型化合物的吸收光谱、基态零场分裂、顺磁g因子及顺磁磁化率、磁化强度等进行了统一的计算,理论结果与实验一致,从而对Ni(mpz)₄Cl₂的光、磁性质作出了完整的、合理的解释。

Abstract: By means of a complete configuration mixing unified crystal field theory for d⁸(D_4h^*),the optical spectra,the ground state ZFS,EPS parameters,the ground state paramagnetic susceptibility and the magnetization of the Ni(mpz)₄Cl₂ compounds are analysed and calculated systematically.Numerical results agree well with the experimental data,so a complete and reasonable explanation is provicled for the magnetic of Ni(mpz)₄Cl₂ compounds.