双原子分子在啁啾激光作用下的经典解离

Classical Dissociation of a Diatomic Molecule with Chirped Pulses

  • 摘要: 采用辛算法及经典理论方法,计算了HF分子在啁啾激光作用下的经典解离,讨论了解离几率随激光强度的变化,以及在相同激光强度下,选取不同的振动态作为初始态时解离几率的变化.

     

    Abstract: A classical trajectory method is used to study a diatomic molecule(HF) interacting with chirped intense laser pulses.In the model,the motion of nuclei is described with classical Hamiltonian canonical equations.The Hamiltonian equation is solved numerically by a symplectic method,and the initial conditions are chosen by a single trajectory in the field-free case at random.The classical dissociation of HF by chirped pulses is evaluated.The dissociation probabilities with different laser intensities are discussed.Dissociation probabilities at different initial states are also investigated.The dissociation process is illustrated by classical phase trajectories and energy versus nuclei separation.

     

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