氢气的直接光解离和自发辐射解离

Direct Photodissociation and Spontaneous Radiative Dissociation of H2

  • 摘要: 作为宇宙中含量最丰富的分子, 氢气(H₂)在天体环境中的演化机制具有重要的研究意义。本文系统的研究了考虑温度效应后H₂ 从基态至激发态和的直接光解离过程,计算了不同温度下的直接光解离截面,并在此基础上评估了黑体辐射场中相应的直接光解离速率。同时,本文还讨论了H₂ 从激发态通过自发辐射跃迁至低能态连续区域的自发辐射解离速率以及激发态的寿命。所有计算均采用最新的高精度分子势能曲线和跃迁偶极矩,所得结果可为氢气分子解离动力学及相关模型研究提供高精度的参考数据。

     

    Abstract: As the most abundant molecule in the universe, molecular hydrogen (H₂) plays a significant role in the evolutionary mechanisms of astrophysical environments. This study systematically investigates the direct photodissociation process of H₂ from the ground state to the excited B and C states, taking into account the effects of temperature. The direct photodissociation cross sections at various temperatures are calculated, and the corresponding dissociation rates in a blackbody radiation field are evaluated accordingly. Additionally, the spontaneous radiative dissociation rates resulting from transitions from excited states to the continuum regions of lower electronic states, as well as the lifetimes of excited states, are discussed. All calculations are based on the latest high-precision molecular potential energy curves and transition dipole moments. The results obtained provide high-accuracy reference data for studies on the dissociation dynamics of molecular hydrogen and related models.

     

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